Across a period, the effective nuclear charge generally?
Aincreases
Bbecomes zero
Cdecreases
Dremains exactly constant
Question 3Single Answer
Across a period, atomic radius generally?
Aremains constant
Bincreases
Cdecreases
Dfirst becomes infinite
Question 4Single Answer
Down a group, atomic radius generally?
Aremains constant
Bincreases
Cdecreases
Dbecomes zero
Question 5Single Answer
The first ionization enthalpy generally increases across a period because of?
Aincreasing effective nuclear charge
Bincreasing shielding by a new shell
Ccomplete absence of electron-electron repulsion
Ddecreasing nuclear charge
Question 6Single Answer
The first ionization enthalpy generally decreases down a group mainly because of?
Aincreased size and shielding
Bdecreased number of shells
Cincreased effective attraction without shielding
Dloss of all core electrons
Question 7Single Answer
Among alkali metals, the lowest first ionization enthalpy is expected toward the?
Atop of the group
Bbottom of the group
Cmiddle only
Dnoble-gas end of the same period
Question 8Single Answer
A cation is usually smaller than its parent atom because?
Aelectron gain increases shielding
Bneutrons expand the electron cloud
Cthe nucleus loses protons
Delectron loss reduces repulsion and may remove the outer shell
Question 9Single Answer
An anion is usually larger than its parent atom because?
Athe principal quantum number always decreases
Ba proton is removed
Cthe nuclear charge increases
Dadded electron-electron repulsion expands the electron cloud
Question 10Single Answer
In an isoelectronic series, ionic radius decreases as?
Anuclear charge increases
Bnumber of electrons increases
Cprincipal shell number increases
Dnuclear charge decreases
Question 11Single Answer
The most electronegative element on the Pauling scale is?
Anitrogen
Bchlorine
Cfluorine
Doxygen
Question 12Single Answer
Electronegativity generally decreases down a group because?
Aeffective nuclear charge becomes infinite
Bnuclear charge decreases to zero
Cvalence shells disappear
Datomic size and shielding increase
Question 13Single Answer
Electron affinity is most directly associated with?
Aaddition of an electron to a gaseous atom
Baddition of a neutron
Cremoval of an electron from a solid
Dremoval of a proton
Question 14Single Answer
The relatively low electron affinity of fluorine compared with chlorine is largely due to?
Agreater electron-electron repulsion in the compact 2p shell
Bfilled d orbitals in fluorine
Cabsence of nuclear charge in fluorine
Dlarger size of fluorine
Question 15Single Answer
The exceptionally high ionization enthalpy of noble gases is related to?
Aabsence of protons
Bsingle valence electrons
Cstable closed-shell configurations
Dvery large atomic radii
Question 16Single Answer
The first ionization enthalpy of Be is higher than that of B mainly because Be has?
Aa filled 2p subshell
Ba filled 2s subshell
Cone fewer proton
Da larger atomic radius
Question 17Single Answer
The first ionization enthalpy of N is higher than that of O mainly because N has?
Aa half-filled 2p subshell
Ba filled 2p subshell
Ca larger principal shell
Dno p electrons
Question 18Single Answer
Lanthanide contraction arises mainly from?
Aloss of all 5d electrons
Bpoor shielding by 4f electrons
Cdecreasing nuclear charge
Dexcellent shielding by 4f electrons
Question 19Single Answer
Diagonal relationship is especially prominent between?
AF and Cl
BBe and Mg
CLi and Mg
DLi and Na
Question 20Single Answer
The inert-pair effect becomes more important down the p-block because?
Athe ns2 pair becomes less available for bonding
Bp orbitals vanish
Celectronegativity always increases
Dall valence electrons become unpaired
Question 21Single Answer
The metallic character generally increases?
Adown a group
Bwith increasing ionization enthalpy
Ctoward fluorine
Dacross a period from left to right
Question 22Single Answer
The nonmetallic character generally increases?
Aacross a period from left to right
Bwith decreasing electronegativity
Cdown alkali-metal group
Dwith increasing atomic radius
Question 23Single Answer
A large jump between successive ionization enthalpies usually indicates?
Aelectron affinity has become positive
Bthe atom has become neutral again
Cnuclear charge has decreased
Dremoval has begun from an inner closed shell
Question 24Single Answer
Slater's rules are used to estimate?
Amolecular symmetry only
Bnuclear spin
Cbond order directly
Dshielding and effective nuclear charge
Question 25Single Answer
The shielding ability of subshells of the same principal shell generally follows?
Ad > s > p > f
Bp > s > f > d
Cs > p > d > f
Df > d > p > s
Question 26Single Answer
The radius commonly assigned to nonbonded atoms in neighboring molecules is the?
Avan der Waals radius
Bcovalent radius
CBohr magneton
Dmetallic radius
Question 27Single Answer
Covalent radius is commonly defined from?
Aelectron affinity
Bhalf the distance between ions in any crystal
Chalf the internuclear distance between identical covalently bonded atoms
Dthe nuclear diameter
Question 28Single Answer
The smallest species among O2-, F-, Na+, and Mg2+ is?
ANa+
BF-
CMg2+
DO2-
Question 29Single Answer
The largest species among N3-, O2-, F-, and Na+ is?
AO2-
BNa+
CF-
DN3-
Question 30Single Answer
The anomalous behavior of second-period elements is strongly related to?
Aabsence of p orbitals
Bvery large size and filled d shells
Csmall size and absence of low-lying d orbitals
Dzero electronegativity
Question 31Single Answer
The maximum covalency shown by second-period elements is limited mainly by?
Alack of accessible d orbitals in the valence shell
Black of s orbitals
Ccomplete shielding
Dabsence of nuclear charge
Question 32Single Answer
The tendency to form multiple pĪ-pĪ bonds is strongest for?
Asecond-period elements
Blanthanides only
Calkali metals only
Dheaviest p-block elements
Question 33Single Answer
The electropositive character is greatest toward the?
Alower-left region of the periodic table
Btop of halogen group
Ccenter of noble-gas group
Dupper-right region
Question 34Single Answer
The electron-gain tendency is generally strongest toward the?
Aupper-right region excluding noble gases
Bmiddle of alkali group
Clanthanide series only
Dlower-left region
Question 35Single Answer
A species with a higher effective nuclear charge on the same shell generally has?
Azero ionization energy
Ba smaller radius
Cthe same radius necessarily
Da larger radius
Question 36Single Answer
The second ionization enthalpy of an alkali metal is very high because it removes an electron from?
Aa noble-gas core
Ba newly added anion orbital
Ca diffuse d orbital
Da singly occupied valence s orbital
Question 37Single Answer
Which option correctly completes the statement: The modern periodic law is based primarily on?
Aneutron number
Batomic mass
Catomic number
Dmass number
Question 38Single Answer
Which option correctly completes the statement: Across a period, the effective nuclear charge generally?
Aremains exactly constant
Bincreases
Cbecomes zero
Ddecreases
Question 39Single Answer
Which option correctly completes the statement: Across a period, atomic radius generally?
Aremains constant
Bdecreases
Cfirst becomes infinite
Dincreases
Question 40Single Answer
Which option correctly completes the statement: Down a group, atomic radius generally?
Adecreases
Bremains constant
Cbecomes zero
Dincreases
Question 41Single Answer
Which option correctly completes the statement: The first ionization enthalpy generally increases across a period because of?
Aincreasing shielding by a new shell
Bcomplete absence of electron-electron repulsion
Cdecreasing nuclear charge
Dincreasing effective nuclear charge
Question 42Single Answer
Which option correctly completes the statement: The first ionization enthalpy generally decreases down a group mainly because of?
Aincreased effective attraction without shielding
Bloss of all core electrons
Cdecreased number of shells
Dincreased size and shielding
Question 43Single Answer
Which option correctly completes the statement: Among alkali metals, the lowest first ionization enthalpy is expected toward the?
Anoble-gas end of the same period
Bbottom of the group
Ctop of the group
Dmiddle only
Question 44Single Answer
Which option correctly completes the statement: A cation is usually smaller than its parent atom because?
Aneutrons expand the electron cloud
Bthe nucleus loses protons
Celectron loss reduces repulsion and may remove the outer shell
Delectron gain increases shielding
Question 45Single Answer
Which option correctly completes the statement: An anion is usually larger than its parent atom because?
Athe principal quantum number always decreases
Badded electron-electron repulsion expands the electron cloud
Ca proton is removed
Dthe nuclear charge increases
Question 46Single Answer
Which option correctly completes the statement: In an isoelectronic series, ionic radius decreases as?
Anuclear charge decreases
Bprincipal shell number increases
Cnuclear charge increases
Dnumber of electrons increases
Question 47Single Answer
Which option correctly completes the statement: The most electronegative element on the Pauling scale is?
Achlorine
Bnitrogen
Coxygen
Dfluorine
Question 48Single Answer
Which option correctly completes the statement: Electronegativity generally decreases down a group because?
Aatomic size and shielding increase
Bnuclear charge decreases to zero
Cvalence shells disappear
Deffective nuclear charge becomes infinite
Question 49Single Answer
Which option correctly completes the statement: Electron affinity is most directly associated with?
Aremoval of an electron from a solid
Bremoval of a proton
Caddition of an electron to a gaseous atom
Daddition of a neutron
Question 50Single Answer
Which option correctly completes the statement: The relatively low electron affinity of fluorine compared with chlorine is largely due to?
Aabsence of nuclear charge in fluorine
Blarger size of fluorine
Cfilled d orbitals in fluorine
Dgreater electron-electron repulsion in the compact 2p shell
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Chemistry
Question 51Single Answer
A physically acceptable wavefunction must be?
Amultivalued everywhere
Bsingle-valued, finite and continuous where the potential is finite
Cinfinite at all boundaries
Ddiscontinuous at every point
Question 52Single Answer
The Born interpretation associates the square modulus of a wavefunction with?
Anuclear charge
Bpotential energy only
Cprobability density
Dclassical trajectory
Question 53Single Answer
An observable in quantum mechanics is represented by?
Aa Hermitian operator
Ba classical orbit
Ca non-Hermitian matrix only
Dan arbitrary complex number
Question 54Single Answer
Eigenvalues of a Hermitian operator are?
Areal
Balways negative
Cundefined
Dalways imaginary
Question 55Single Answer
Two observables can have simultaneous exact eigenvalues when their operators?
Aare identical to zero
Banticommute only
Ccommute
Dare non-Hermitian
Question 56Single Answer
The commutator of position and its conjugate momentum is?
Aequal to the identity without an imaginary factor
Bundefined for all states
Calways zero
Dnonzero
Question 57Single Answer
The uncertainty principle reflects?
Athermal expansion only
Bnoncommutation of conjugate observables
Cclassical friction
Dinstrumental error only
Question 58Single Answer
The Hamiltonian operator represents?
Alinear momentum only
Bspin only
Cprobability only
Dtotal energy
Question 59Single Answer
A stationary state is an eigenstate of?
Athe time-independent Hamiltonian
Bposition only
Cparity only
Dtemperature
Question 60Single Answer
Normalization of a wavefunction ensures that?
Athe wavefunction is real
Btotal probability is unity
Cenergy is zero
Dmomentum is infinite
Question 61Single Answer
Orthogonal eigenfunctions have?
Aunit overlap always
Binfinite overlap
Cidentical eigenvalues necessarily
Dzero overlap integral
Question 62Single Answer
For a particle in a one-dimensional box, the wavefunction at infinite walls is?
Amaximum
Bundefined
Cperiodic with nonzero boundary value
Dzero
Question 63Single Answer
Energy levels of a particle in a box become more widely separated as?
Aparticle mass becomes infinite only
Bthe box becomes larger
Cthe box becomes smaller
Dquantum number decreases to zero
Question 64Single Answer
A two-dimensional square box can exhibit?
Acontinuous energies only
Bonly one allowed state
Cno degeneracy under any condition
Ddegeneracy from different quantum-number pairs
Question 65Single Answer
For a three-dimensional rectangular box, separability means the wavefunction can be written as?
Aa classical trajectory
Ba constant only
Ca sum of nuclear charges
Da product of one-dimensional functions
Question 66Single Answer
The ground-state energy of a quantum harmonic oscillator is?
Aexactly zero
Bnegative infinite
Cundefined
Dnonzero
Question 67Single Answer
The nonzero ground-state energy of a harmonic oscillator is called?
Azero-point energy
Bactivation energy
Cionization energy
Dlattice energy
Question 68Single Answer
Adjacent harmonic-oscillator levels in the ideal model are?
Adegenerate with all other levels
Bequally spaced
Crandomly spaced
Dcontinuously distributed
Question 69Single Answer
The rigid-rotor model assumes?
Afixed bond length
Bno angular momentum
Czero moment of inertia
Dcontinuously changing bond length
Question 70Single Answer
Rotational energy levels of a rigid rotor depend on?
Aprincipal quantum number only
Bangular momentum quantum number
Cnuclear charge only
Delectron spin only
Question 71Single Answer
Hydrogenic orbitals are eigenfunctions of?
Athe hydrogen-atom Hamiltonian
Ba classical Kepler orbit
Ctemperature operator
Dviscosity operator
Question 72Single Answer
The principal quantum number primarily determines?
Anuclear spin
Bhydrogenic energy and shell
Cspin orientation only
Dorbital orientation only
Question 73Single Answer
The azimuthal quantum number is associated with?
Anuclear mass
Btemperature
Corbital angular momentum
Delectron charge
Question 74Single Answer
The magnetic quantum number specifies?
Aelectron mass
Borientation of orbital angular momentum
Cspin magnitude
Dradial node count only
Question 75Single Answer
Electron spin is?
Aa vibrational coordinate
Bliteral classical spinning of a charged sphere
Corbital motion only
Dan intrinsic angular momentum
Question 76Single Answer
For an electron, the spin quantum number is?
Atwo
Bzero
Cone-half
Done
Question 77Single Answer
Quantum tunneling allows a particle to?
Amove faster than light necessarily
Blose all wave character
Cviolate energy conservation
Dpenetrate a classically forbidden barrier
Question 78Single Answer
Tunneling probability generally increases when a barrier becomes?
Awider
Binfinitely high
Cthinner
Dmore massive
Question 79Single Answer
Parity describes behavior of a wavefunction under?
Atemperature change
Btime translation only
Cspatial inversion
Dparticle exchange only
Question 80Single Answer
A complete set of commuting observables is used to?
Aremove normalization
Bmake all operators identical
Celiminate all uncertainty
Dlabel quantum states uniquely
Question 81Single Answer
Which option correctly completes the statement: A physically acceptable wavefunction must be?
Ainfinite at all boundaries
Bdiscontinuous at every point
Csingle-valued, finite and continuous where the potential is finite
Dmultivalued everywhere
Question 82Single Answer
Which option correctly completes the statement: The Born interpretation associates the square modulus of a wavefunction with?
Apotential energy only
Bclassical trajectory
Cprobability density
Dnuclear charge
Question 83Single Answer
Which option correctly completes the statement: An observable in quantum mechanics is represented by?
Aa classical orbit
Ban arbitrary complex number
Ca non-Hermitian matrix only
Da Hermitian operator
Question 84Single Answer
Which option correctly completes the statement: Eigenvalues of a Hermitian operator are?
Aundefined
Breal
Calways imaginary
Dalways negative
Question 85Single Answer
Which option correctly completes the statement: Two observables can have simultaneous exact eigenvalues when their operators?
Acommute
Bare non-Hermitian
Care identical to zero
Danticommute only
Question 86Single Answer
Which option correctly completes the statement: The commutator of position and its conjugate momentum is?
Anonzero
Bundefined for all states
Cequal to the identity without an imaginary factor
Dalways zero
Question 87Single Answer
Which option correctly completes the statement: The uncertainty principle reflects?
Athermal expansion only
Binstrumental error only
Cnoncommutation of conjugate observables
Dclassical friction
Question 88Single Answer
Which option correctly completes the statement: The Hamiltonian operator represents?
Atotal energy
Bprobability only
Clinear momentum only
Dspin only
Question 89Single Answer
Which option correctly completes the statement: A stationary state is an eigenstate of?
Aparity only
Btemperature
Cthe time-independent Hamiltonian
Dposition only
Question 90Single Answer
Which option correctly completes the statement: Normalization of a wavefunction ensures that?
Aenergy is zero
Bmomentum is infinite
Ctotal probability is unity
Dthe wavefunction is real
Question 91Single Answer
Which option correctly completes the statement: Orthogonal eigenfunctions have?
Aunit overlap always
Bidentical eigenvalues necessarily
Czero overlap integral
Dinfinite overlap
Question 92Single Answer
Which option correctly completes the statement: For a particle in a one-dimensional box, the wavefunction at infinite walls is?
Aperiodic with nonzero boundary value
Bzero
Cmaximum
Dundefined
Question 93Single Answer
Which option correctly completes the statement: Energy levels of a particle in a box become more widely separated as?
Aparticle mass becomes infinite only
Bthe box becomes smaller
Cquantum number decreases to zero
Dthe box becomes larger
Question 94Single Answer
Which option correctly completes the statement: A two-dimensional square box can exhibit?
Ano degeneracy under any condition
Bonly one allowed state
Cdegeneracy from different quantum-number pairs
Dcontinuous energies only
Question 95Single Answer
Which option correctly completes the statement: For a three-dimensional rectangular box, separability means the wavefunction can be written as?
Aa product of one-dimensional functions
Ba sum of nuclear charges
Ca classical trajectory
Da constant only
Question 96Single Answer
Which option correctly completes the statement: The ground-state energy of a quantum harmonic oscillator is?
Aundefined
Bexactly zero
Cnonzero
Dnegative infinite
Question 97Single Answer
Which option correctly completes the statement: The nonzero ground-state energy of a harmonic oscillator is called?
Aionization energy
Blattice energy
Cactivation energy
Dzero-point energy
Question 98Single Answer
Which option correctly completes the statement: Adjacent harmonic-oscillator levels in the ideal model are?
Aequally spaced
Bcontinuously distributed
Cdegenerate with all other levels
Drandomly spaced
Question 99Single Answer
Which option correctly completes the statement: The rigid-rotor model assumes?
Acontinuously changing bond length
Bfixed bond length
Czero moment of inertia
Dno angular momentum
Question 100Single Answer
Which option correctly completes the statement: Rotational energy levels of a rigid rotor depend on?
Anuclear charge only
Bangular momentum quantum number
Cprincipal quantum number only
Delectron spin only
Question 101Single Answer
The suffix used for an aldehyde as the principal functional group is?
A-oic acid
B-al
C-one
D-ol
Question 102Single Answer
The suffix used for a ketone as the principal functional group is?
A-one
B-ol
C-amine
D-al
Question 103Single Answer
The prefix for an -OH group when it is not principal is?
Ahydroxy
Bformyl
Coxo
Damino
Question 104Single Answer
The prefix for a carbonyl group when it is not principal is?
Aamino
Bhydroxy
Cmercapto
Doxo
Question 105Single Answer
In IUPAC nomenclature, the parent chain is selected primarily to include?
Athe alphabetically first substituent
Bthe lowest molecular mass fragment
Cthe principal functional group
Dthe maximum number of methyl groups only
Question 106Single Answer
The stereodescriptors R and S specify?
Aring fusion only
Babsolute configuration at a stereogenic center
Calkene geometry only
Drelative configuration of sugars only
Question 107Single Answer
The E descriptor for an alkene indicates that higher-priority groups are?
Aboth equatorial
Bboth axial
Con the same side
Don opposite sides
Question 108Single Answer
The Z descriptor for an alkene indicates that higher-priority groups are?
Aboth absent
Bnecessarily trans to hydrogen
Con opposite sides
Don the same side
Question 109Single Answer
CIP priority is assigned first according to?
Abond length
Batomic number of the directly attached atom
Calphabetical order
Datomic mass of the whole molecule
Question 110Single Answer
For isotopes of the same element, higher CIP priority is generally given to?
Aboth always have identical priority
Bthe isotope of lower mass number
Cthe isotope of higher mass number
Dthe radioactive isotope only
Question 111Single Answer
A spiro compound contains?
Atwo rings sharing two adjacent atoms
Btwo rings sharing one common atom
Cno ring junction
Dthree fused benzene rings
Question 112Single Answer
A bridged bicyclic compound has?
Aonly one carbon-carbon bond
Bone atom common to both rings only
Ctwo bridgehead atoms connected by three distinct paths
Dno bridgehead atoms
Question 113Single Answer
In bicyclo nomenclature, the numbers in brackets denote?
Anumbers of heteroatoms only
Bnumbers of atoms in the three bridges excluding bridgeheads
Cring strain energies
Doxidation states
Question 114Single Answer
The D/L system for carbohydrates is related historically to?
Aconfiguration relative to glyceraldehyde
Bmolecular mass
CE/Z geometry
Dsign of optical rotation necessarily
Question 115Single Answer
The sign of optical rotation is?
Aalways positive for R
Bnot determined by the R/S descriptor alone
Calways negative for S
Didentical to D/L
Question 116Single Answer
Alpha and beta descriptors in cyclic sugars describe?
Aabsolute R/S configuration of every center
Banomeric configuration
Calkene geometry
Dchain length
Question 117Single Answer
In carbohydrate nomenclature, anomers differ at?
Athe carbonyl oxygen
Bthe anomeric carbon
Cthe terminal primary carbon only
Devery stereocenter
Question 118Single Answer
A locant in an IUPAC name identifies?
Aoptical rotation
Bthe position of a substituent or functional feature
Cmolecular mass
Dboiling point
Question 119Single Answer
Multiplicative prefixes di-, tri-, and tetra- indicate?
Aring size only
Boxidation state
Cnumber of identical substituents
Dstereochemistry
Question 120Single Answer
Alphabetization of simple substituents normally ignores?
Aheteroatom names
Bmultiplicative prefixes such as di- and tri-
Call locants
Dthe first letter of the substituent
Question 121Single Answer
The prefix cyclo- indicates?
Aan aromatic system only
Ba ring parent structure
Can acyclic parent
Da radical ion
Question 122Single Answer
The ending -ene indicates?
Aa carbon-carbon triple bond
Ban amide
Can alcohol
Da carbon-carbon double bond
Question 123Single Answer
The ending -yne indicates?
Aan ether
Ba carbon-carbon triple bond
Ca carbon-carbon double bond
Da ketone
Question 124Single Answer
A molecule named with both -ene and -yne contains?
Aboth double and triple carbon-carbon bonds
Ba peroxide
Conly aromatic bonds
Donly single bonds
Question 125Single Answer
The descriptor cis in a simple disubstituted ring indicates substituents are?
Anecessarily equatorial
Bnecessarily axial
Con opposite faces
Don the same face of the ring
Question 126Single Answer
Which option correctly completes the statement: The suffix used for an aldehyde as the principal functional group is?
A-al
B-oic acid
C-one
D-ol
Question 127Single Answer
Which option correctly completes the statement: The suffix used for a ketone as the principal functional group is?
A-one
B-al
C-amine
D-ol
Question 128Single Answer
Which option correctly completes the statement: The prefix for an -OH group when it is not principal is?
Aformyl
Bamino
Chydroxy
Doxo
Question 129Single Answer
Which option correctly completes the statement: The prefix for a carbonyl group when it is not principal is?
Aoxo
Bhydroxy
Cmercapto
Damino
Question 130Single Answer
Which option correctly completes the statement: In IUPAC nomenclature, the parent chain is selected primarily to include?
Athe principal functional group
Bthe maximum number of methyl groups only
Cthe lowest molecular mass fragment
Dthe alphabetically first substituent
Question 131Single Answer
Which option correctly completes the statement: The stereodescriptors R and S specify?
Arelative configuration of sugars only
Balkene geometry only
Cring fusion only
Dabsolute configuration at a stereogenic center
Question 132Single Answer
Which option correctly completes the statement: The E descriptor for an alkene indicates that higher-priority groups are?
Aon opposite sides
Bboth axial
Cboth equatorial
Don the same side
Question 133Single Answer
Which option correctly completes the statement: The Z descriptor for an alkene indicates that higher-priority groups are?
Aon opposite sides
Bon the same side
Cnecessarily trans to hydrogen
Dboth absent
Question 134Single Answer
Which option correctly completes the statement: CIP priority is assigned first according to?
Aalphabetical order
Batomic mass of the whole molecule
Cbond length
Datomic number of the directly attached atom
Question 135Single Answer
Which option correctly completes the statement: For isotopes of the same element, higher CIP priority is generally given to?
Athe radioactive isotope only
Bboth always have identical priority
Cthe isotope of higher mass number
Dthe isotope of lower mass number
Question 136Single Answer
Which option correctly completes the statement: A spiro compound contains?
Ano ring junction
Btwo rings sharing two adjacent atoms
Cthree fused benzene rings
Dtwo rings sharing one common atom
Question 137Single Answer
Which option correctly completes the statement: A bridged bicyclic compound has?
Aonly one carbon-carbon bond
Bone atom common to both rings only
Ctwo bridgehead atoms connected by three distinct paths
Dno bridgehead atoms
Question 138Single Answer
Which option correctly completes the statement: In bicyclo nomenclature, the numbers in brackets denote?
Aoxidation states
Bnumbers of heteroatoms only
Cnumbers of atoms in the three bridges excluding bridgeheads
Dring strain energies
Question 139Single Answer
Which option correctly completes the statement: The D/L system for carbohydrates is related historically to?
Asign of optical rotation necessarily
Bconfiguration relative to glyceraldehyde
Cmolecular mass
DE/Z geometry
Question 140Single Answer
Which option correctly completes the statement: The sign of optical rotation is?
Aidentical to D/L
Balways positive for R
Calways negative for S
Dnot determined by the R/S descriptor alone
Question 141Single Answer
Which option correctly completes the statement: Alpha and beta descriptors in cyclic sugars describe?
Aalkene geometry
Banomeric configuration
Cabsolute R/S configuration of every center
Dchain length
Question 142Single Answer
Which option correctly completes the statement: In carbohydrate nomenclature, anomers differ at?
Aevery stereocenter
Bthe terminal primary carbon only
Cthe anomeric carbon
Dthe carbonyl oxygen
Question 143Single Answer
Which option correctly completes the statement: A locant in an IUPAC name identifies?
Aoptical rotation
Bmolecular mass
Cthe position of a substituent or functional feature
Dboiling point
Question 144Single Answer
Which option correctly completes the statement: Multiplicative prefixes di-, tri-, and tetra- indicate?
Aring size only
Bnumber of identical substituents
Cstereochemistry
Doxidation state
Question 145Single Answer
Which option correctly completes the statement: Alphabetization of simple substituents normally ignores?
Aall locants
Bmultiplicative prefixes such as di- and tri-
Cthe first letter of the substituent
Dheteroatom names
Question 146Single Answer
Which option correctly completes the statement: The prefix cyclo- indicates?
Aan aromatic system only
Ba ring parent structure
Ca radical ion
Dan acyclic parent
Question 147Single Answer
Which option correctly completes the statement: The ending -ene indicates?
Aa carbon-carbon double bond
Ba carbon-carbon triple bond
Can amide
Dan alcohol
Question 148Single Answer
Which option correctly completes the statement: The ending -yne indicates?
Aa carbon-carbon triple bond
Ba carbon-carbon double bond
Can ether
Da ketone
Question 149Single Answer
Which option correctly completes the statement: A molecule named with both -ene and -yne contains?
Aonly single bonds
Bboth double and triple carbon-carbon bonds
Conly aromatic bonds
Da peroxide
Question 150Single Answer
Which option correctly completes the statement: The descriptor cis in a simple disubstituted ring indicates substituents are?