10-6 M NaOH is diluted 100 times. The pH of the diluted base is
Abetween 7 and 8
Bbetween 5 and 6
Cbetween 6 and 7
Dbetween 10 and 11
Question 2Single Answer
In the electrolysis of acidulated water, it is desired to obtain 1.12 cc of hydrogen per second under STP condition. The current to be passed is
A1.93 A
B9.65 A
C19.3 A
D0.965 A
Question 3Single Answer
The one which decreases with dilution is
Amolar conductance
Bconductance
Cspecific conductance
Dequivalent conductance
Question 4Single Answer
Vapour pressure of pure ‘A’ is 70 mm of Hg at 25oC. It forms an ideal solution with ‘B’ in which mole fraction of A is 0.8. if the vapour pressure of the solution is 84 mm of Hg at 25oC, the vapour pressure of pure ‘B’ at 25oC is
A28 mm
B56 mm
C70 mm
D140 mm
Question 5Single Answer
A 6% solution of urea is isotonic with
A1 M solution of glucose
B0.05 M solution of glucose
C6% solution of glucose
D25% solution of glucose
Question 6Single Answer
In countries nearer to polar region, the roads are sprinkled with CaCl2. This is
Ato minimise the wear and tear of the roads
Bto minimise the snow fall
Cto minimise pollution
Dto minimise the accumulation of dust on the road
Question 7Single Answer
A compound of ‘A’ and ‘B’ crystallises in a cubic lattice in which ‘A’ atoms occupy the lattice points at the corners of the cube. The ‘B’ atoms occupy the centre of each face of the cube. The probable empirical formula of the compound is
AAB2
BA2B
CAB
DAB3
Question 8Single Answer
In electrophilic aromatic substitution reaction, the nitro group is meta directing because it
Adecreases electron density at ortho and para positions
Bdecreases electron density at meta position
Cincreases electron density at meta position
Dincreases electron density at ortho and para position
Question 9Single Answer
The best method for the conversion of an alcohol into an alkyl chloride is by treating the alcohol with
APCI5
BPCI3
CSOCl2 in presence of pyridine
Ddry HCl in the presence of anhydrous ZnCl2
Question 10Single Answer
The carbon bond length in benzene is
Ain between C2H6 and C2H4
Bsame as in C2H4
Cin between C2H6 and C2H2
Din between C2H4 and C2H2
Question 11Single Answer
The compound which is not formed during the dry distillation of a mixture of calcium formate and calcium acetate is
Amethanal
Bpropanal
Cpropanone
Dethanal
Question 12Single Answer
An organic compound x is oxidised by using acidified K2Cr2O7. The product obtained reacts with phenyl hydrazine but does not answer silver mirror test. The possible structured of X is
ACH3CH2OH
BCH3 – C – CH3
C(CH3)2CHOH
DCH3CHO
Question 13Single Answer
Arrange the following in the increasing of their. Basic strengths CH3NH2, (CH3)2NH, (CH3)2N, NH3
ANH3, < (CH3)3N < (CH3)2NH < CH3NH2
BNH3 < (CH3)3N < CH3NH2 < (CH3)2NH
C(CH3)3N < NH3 < CH3NH2 < (CH3)2NH
DCH3NH2 < (CH3)2NH < (CH3)3N , NH3
Question 14Single Answer
The one which has least iodine value is
Asunflower oil
Bginger oil
Cghee
Dgroundnut oil
Question 15Single Answer
A diabetic person carries a packet of glucose with him always, because
Aglucose reduces the blood sugar level slowly
Bglucose increases the blood sugar level slowly
Cglucose reduces the blood sugar level
Dglucose increases the blood sugar level almost instantaneously
Question 16Single Answer
There are 20 naturally occurring among acids. The maximum number of tripeptides than can be obtained is
A8000
B6470
C7465
D5360
Question 17Single Answer
At what temperature ill the RMS velocity of SO2 be the same as that of O2 at 303 K ?
A403 K
B303 K
C606 K
D273 K
Question 18Single Answer
Phenol is treated with bromine water and shaken well. The white precipitate formed during the process is
Am–bromophenol
B2, 4, 6 tribromophenol
C2-4 dibromophenol
DA mixture of o-and p-bromophenols
Question 19Single Answer
In thermite process the metal used as reducing agent is:
ANickel
BZinc
CSodium
DAluminium
Question 20Single Answer
Which of the following compounds on boiling with alkaline KMnO4 and subsequent acidification will not give benzoic acid?
ABenzyl alcohol
BAcetophenone
CAnisole
DToluene
Question 21Single Answer
The base present in DNA, but not in RNA is:
AGuanine
BAdenine
CUracil
DThymine
Question 22Single Answer
The total number of lattice arrangements in different crystal system is:
A7
B3
C8
D14
Question 23Single Answer
Alcoholic potash is used to bring about :
ADehydrogenation
BDehydration
CDehydrohalogenation
DDehalogenation
Question 24Single Answer
Which of the following is the correct statement?
AOrder of a reaction has always an integral value
BMechanism of a reaction proposed is always final
CZero order reactions are multi-step reactions
DOrder of reaction can be predicted even without knowing the rate law
Question 25Single Answer
The unit of quantity of electricity is:
AOhm
BAmpere
CCoulomb
DVolt
Question 26Single Answer
Which of the following organic compounds answers both iodoform test and fehling’s test ?
AMethanal
BEthanol
CPropane
DEthanal
Question 27Single Answer
10 dm3 of N2 gas and 10 dm3 of gas X at the same temperature and pressure contain the same number of molecules.
ANO
BH2
CCO2 or CO
DAll of these
Question 28Single Answer
When the electrons of hydrogen atoms return to L shell from shells of higher energy, we get a series of lines in the spectrum. This series is called
ABalmer series
BLyman series
CBracket series
DPaschen series
Question 29Single Answer
The alcohol obtained by the hydrolysis of oils and fats is:
AGlycol
BGlycerol
CPropanol
DPentanol
Question 30Single Answer
Which of the following alloys is used for making magnets for hearing aids?
AAlnico
BGerman silver
CInvar
DMonel metal
Question 31Single Answer
One dm3 of 2M ethanoic acid is mixed with one dm3 of 3M ethanol to form an easter
CH3COOH + C2H5OH → CH3COOC2H5 +H2O
The decrease in the initial rate if each solution is diluted with an equal volume of water would be
A2 times
B4 times
C0.25 times
D0.5 times
Question 32Single Answer
Which one of the following can be classified as a Bronstead base?
ANO3-
BH3O+
CCH3COOH
DNH4+
Question 33Single Answer
Gold sol is an electronegative sol. The amount of electrolyte required to coagulate a certain amount of gold sol is minimum in the case of :Γ’β¬βΉ
ACaCl2
BNaCl
CAlCl3
DNa2SO4
Question 34Single Answer
Aluminium displaces hydrogen from acids, but copper does not. A Galvanic cell prepared by combining Cu/Cu2+ and Al/Al3+ has an emf of 2.0 V at 298 K. If the potential of copper electrode is +0.34 V, that of aluminium electrode is:
A– 2.3 V
B+ 2.34 V
C– 1.66 V
D+ 1.66 V
Question 35Single Answer
1.5 moles of O2 combine with Mg to form the oxide MgO. The mass of Mg that has combined is (Mg = 24):
A72 g
B36 g
C48 g
D24 g
Question 36Single Answer
How much of NaOH is required to neutralize 1500 cm3 of 0.1 N HCI?(Na = 23):
A60 g
B6 g
C4 g
D40 g
Question 37Single Answer
The boiling point of water is exceptionally high because:
AWater molecule is not linear
BWater molecule is linear
CThere is covalent bond between H and O
DWater molecules associate due to hydrogen bonding
Question 38Single Answer
P4O10 is not used with to dry NH3 gas because:
AP4O10 is basic and NH3 is acidic
BP4O10 is acidic and NH3 is basic
CP4O10 is not a drying agent
DP4O10 reacts with moisture in NH3
Question 39Single Answer
A radioactive isotope has a half-life of 10 years. What percentage of the original amount of it remain after 20 years:
A1
B12.5
C8
D25
Question 40Single Answer
75% of a first order reaction is completed in 30 minutes. What is the time required for 93.75% of the reaction (in minutes)?
A45
B120
C90
D60
Question 41Single Answer
Excess of Na+ ions in our system causes:
AHigh B.P.
BLow B.P.
CDiabetes
DAnaemia
Question 42Single Answer
Which of the following is the most active chemically?
AChlorine
BFlourine
CLithium
DIodine
Question 43Single Answer
Which among the following is a Noble Gas?
ANitrogen
BHydrogen
COxygen
DHelium
Question 44Single Answer
Which among the following is known as White Vitriol?
AZinc Sulphate
BZinc Chloride
CZinc Phosphate
DZinc oxide
Question 45Single Answer
The oxidation number and the electronic configuration of sulphur in H2SO4 is:
A+ 4; 1s2 2s2 2p6 3s2
B+2; +6; 1s2 2s2 2p6 3s2 3p2
C+3; 1s2 2s2 2p6 3s2 3p1
D+6; 1s2 2s2 2p6
Question 46Single Answer
The mass of 112 cm3 of CH4 gas at STP is:
A0.16 g
B0.8 g
C0.08 g
D1.6 g
Question 47Single Answer
The volume of water to be added to 100 cm3 of 0.5 N H2SO4 to get decinormal concentration is:
A400 cm3
B500 cm3
C450 cm3
DΓ’β¬βΉ100 cm3
Question 48Single Answer
Reactions that have standard free energy changes less than zero always have equilibrium constant equal to
Aunity
Bgreater than unity
Cless than unity
Dzero
Question 49Single Answer
In order to decompose 9g water 142.5 kJ heat is required. Hence the enthalpy of formation of water is:
A– 142.5 kJ
B+ 142.5 kJ
C– 285 kJ
D+ 285 kJ
Question 50Single Answer
A quantity of PCl5 was heated in a 10 dm3 vessel at 2500 C PCl5 (g) PCl3 (g) + Cl2 (g) At equilibrium the vessel contains 0.1 mole of PCl5 and 0.2 mole of Cl2. The equilibrium constant of the reaction is:
A0.05
B0.02
C0.025
D0.04
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Chemistry
Question 51Single Answer
Which among the following species has the highest ionization potential?
AB
BLi
CNe
DF
Question 52Single Answer
Which one of the following metallic hydroxides does not dissolve in sodium hydroxide solution?
AZn(OH)2
BAl(OH)3
CFe(OH)3
DPb(OH)2
Question 53Single Answer
IUPAC name of K3Fe(CN)6 is:
APotassium ferricyanide
BHexacyano ferrate (III)
CPotassium hexacyno ferrate (III)
DPotassium hexacyno ferrate (II)
Question 54Single Answer
Unpleasant smell of carbylamines is obtained when chloroform and alcoholic KOH are heated with:
AAny aliphatic amine
BAny amine
CAny primary amine
DAny aromatic amine
Question 55Single Answer
Which of the following is an aldohexose?
ACellulose
BSucrose
CGlucose
DRaffinose
Question 56Single Answer
When a mixture of calcium acetate and calcium formate is dry distilled, the product formed as:
AEthanal
BButanone
CMethanal
DAcetophenone
Question 57Single Answer
The test used for identifying peptide linkage in proteins is:
ABorsche’s test
BMolisch’s test
CNinhydrin test
DBiuret test
Question 58Single Answer
Which of the following is not used to distinguish ethane from ethane?
AIodine in CCl4
BBromine in CCl4
CAlkaline KMnO4
DAmmonical Cu2Cl2
Question 59Single Answer
To get a n-type doped semiconductor, impurity to be added to silicon should have the following number of valence electrons:
A1
B3
C5
D2
Question 60Single Answer
Solubility)s) of CaF2 in terms of its solubility product is given a
As = (Ksp)1/3
Bs = (Ksp /2)1/3
Cs = (Ksp/4)1/3
Ds = (Ksp/2)1/2
Question 61Single Answer
5 moles of SO2 and 5 moles of O2 are allowed to react to form SO3 in a closed vessel. At the equilibrium stage 60% of SO2 is used up. The total number of mole of SO2, O2 and SO3 in the vessel now is:
A10.0
B8.5
C10.5
D3.9
Question 62Single Answer
A base, as defined by Bronsted theory, is a substance which can
Aaccept protons
Bdonate protons
Close a pair of electrons
Dgain a pair of electrons
Question 63Single Answer
In the case of small cuts bleeding is stopped by applying potash alum. Here alum acts as:
AFungicide
BDisinfectant
CGermicide
DCoagulating agent
Question 64Single Answer
“It is impossible to determine simultaneously the position and velocity of small particles such as electron”. It is a statement of
AHund’s rule
BAufbau’s principle
CPauli’s rule
DHeisenberg’s uncertainty principle
Question 65Single Answer
The percentage of N2 in urea is about:
A28
B18
C85
D46
Question 66Single Answer
When salicyclic acid is distilled with zinc dust, the product obtained is:
AZinc salicylate
BSalicylaldehyde
CPhenol
DBenzoic acid
Question 67Single Answer
On heating ethanol with excess of conc. H2SO4 at 1700 C, the product obtained is:
AEthene
BEthoxy ethane
CEthyne
DEthane
Question 68Single Answer
To calculate the amount of work done in joules during reversible isothermal expansion of an ideal gas, the volume must be expressed in:
ADm3 only
BM3 only
CAny unit
DCm3 unit
Question 69Single Answer
The quantity of electricity required to liberate 112 cm3 of hydrogen at STP from acidified water is:
A965 coulombs
B1 faraday
C0.1 faraday
D96500 coulombs
Question 70Single Answer
Hydrogen ion concentration of an aqueous solution is 1 × 10-4 M. The solution is diluted with equal volume of water. Hydroxyl ion concentration of the resultant solution in terms of mol dm-3 is:
A1 × 10-8
B1 × 10-6
C2 × 10-10
D0.5 × 10-10
Question 71Single Answer
The shape of cuprammonium ion is:
ATrigonal
BTetrahedral
COctahedral
DSquare planar
Question 72Single Answer
The enthalpy of combustion of C6H6 (l) is -3250 kJ. When 0.39 g of benzene is burnt in excess of oxygen in an open vessel, the amount of heat liberated is:
A16.25 J
B16.25 kJ
C32.5 J
D32.5 kJ
Question 73Single Answer
The oxidation number and the electronic configuration of sulphur in H2SO4 is:Γ’β¬βΉ
A+ 4; 1s2 2s2 2p6 3s2
B+2; +6; 1s2 2s2 2p6 3s2 3p2
C+3; 1s2 2s2 2p6 3s2 3p1
D+6; 1s2 2s2 2p6
Question 74Single Answer
The solubility product of a binary weak electrolyte is 4 × 10-10 at 298 K. Its solubility in mol dm-3 at the same temperature is:
A4 × 10-5
B2 × 10-5
C8 × 10-10
D16 × 10-20
Question 75Single Answer
Propane is the product obtained by dehydrogenation of:
A2 v- propanol
B1 – propanol
CPropanol
DN – propyl alcohol
Question 76Single Answer
To get DDT chlorobenzene has to react with the following compound in the pressure of concentrated sulphric acid:
ATrichloro ethane
BDichloro acetone
CDichloro acetaldehyde
DTrichloro acetaldehyde
Question 77Single Answer
Glacial acetic acid is obtained by:
AChemically separating acetic acid
BTreating vinegar with dehydrating agents
CCrystallising, separating and melting acetic acid
DDistilling vinegar
Question 78Single Answer
Hypothyroidism is caused by the deficiency of :
AThyroxine
BGlucocorticoid
CVitamin B-12
DAdrenalin
Question 79Single Answer
A food additive that also acts as an anti-oxidant is :
ASugar syrup
BSalt
CBHA
DSaccharin
Question 80Single Answer
Which of the following monomers can undergo condensation polymerisation ?
AIsoprene
BPropene
CStyrene
DGlycine
Question 81Single Answer
Schottky defect in a crystal is observed when ,
AUnequal number of cations and anions are missing from the lattice
BEqual number of cations and anions are missing from the lattice
CAn ion leaves its normal site and occupies an interstitial site
DNo ion is missing from its lattice site
Question 82Single Answer
The simplest way to check whether a system is colloidal is by
AElectrodialysis
BFinding out particle size
CTyndall effect
DBrownian movement
Question 83Single Answer
An example for a strong electrolyte is:
AUrea
BAmmonium hydroxide
CSugar
DSodium acetate
Question 84Single Answer
An example of a salt that will not hydrolyse is
ACH3COONH4
BCH3COOK
CNH4CI
DKCI
Question 85Single Answer
C14 is
AA natural non – radioactive isotope
BAn artificial non – radioactive isotope
CAn artificial radioactive isotope
DA natural radioactive isotope
Question 86Single Answer
A cuprous ore among the following is
ACuprite
BMalachite
CChalcopyrites
DAzurite
Question 87Single Answer
Smallest among these species is:
ALithium
BLithium ion
CHydrogen
DHelium
Question 88Single Answer
Sodium chloride is an ionic compound where as hydrogen chloride gas is mainly convalent because
AElectronegativity difference in the case of hydrogen in less than 2.1
BHydrogen chloride is a gas
CHydrogen is a non metal
DSodium is reactive
Question 89Single Answer
Convalent compounds have low melting point because
AConvalent molecules are held by weak van der waal’s force of attraction
BConvalent bond is less exothermic
CConvalent bond is weaker than ionic bond
DConvalent molecules have definite shape
Question 90Single Answer
Which of the following is an alloy of aluminium?
Amagnalium
Bduralumin
Cbrass
Dboth ‘a’ and ‘b’
Question 91Single Answer
A neutral fertilizer among these compounds is
AAmmonium nitrate
BUrea
CCAN
DAmmonium sulphate
Question 92Single Answer
A condensation polymer among the following polymers is
ATeflon
BPolysterene
CPVC
DDecron
Question 93Single Answer
A compound that undergoes bromination easily is:
AToluene
BBenzoic acid
CPhenol
DBenzene
Question 94Single Answer
A sugar that is not a disaccharide among the following is
AGalactose
BLactose
CMaltose
DSucrose
Question 95Single Answer
Drying soil invariably contains
AButyric acid
BStearic acid
CLauric acid
DLinoleic acid
Question 96Single Answer
Hetrocyclic amino acid among these compound is
ALysine
BTyrosine
CProline
DSerine
Question 97Single Answer
Aluminium oxide is not reduced by chemical reactions since
AReducing agent contaminate
BThe process pollute the environment
CAluminium oxide is highly stable
DAluminium oxide is reactive
Question 98Single Answer
Iron loses magnetic property at
AMelting point
B1000 K
CCurie point
DBoiling point
Question 99Single Answer
An example for a double salt is
APotassium ferricyanide
BCobalt hexamine chloride
CCuprous sulphate
DMohr’s salt
Question 100Single Answer
The set of compounds in which the reactivity of halogen atom in the ascending order is
AViny1 chloride, chloroethane, chlorobenzene
BViny1 chloride, chlorobenzene, chloroethane
Cchloroethane, chlorobenzene, Viny1 chloride
Dchlorobenzene, Viny1 chloride, chloroethane
Question 101Single Answer
methanol is
ACH3CHO
BCH3COCH3
CCH2OH
DHCHO
Question 102Single Answer
In the case of auto catalysis
AProduct catalysis
BSolvent catalysis
CReactant catalysis
DHeat produced in the reaction catalysis
Question 103Single Answer
The mass of 112 cm3 of CH4 gas at STP is:
A0.16 g
B0.8 g
C0.08 g
D1.6 g
Question 104Single Answer
Order to reaction is decided by
AMolecularity
BPressure
CTemperature
DMechanism of reaction as well as relative concentration of reactants
Question 105Single Answer
Half-life of a reaction is found to be inversely proportional to the cube of initial concentration. The order of reaction is
A5
B2
C4
D3
Question 106Single Answer
Which among the following statement is false?
AThe adsorption may be monolayered or multilayered
BParticle size of adsorbent will not affect the amount of adsorption
CIncrease of pressure increases amount of adsorption
DIncrease of temperature may decrease the amount of adsorption
Question 107Single Answer
Purine derivative among the following bases is
ACytosine
BGuanine
CUracil
DThymine
Question 108Single Answer
A drug that is antipyretic as well as analgesic is
APenicillin
BChloroquin
CPara acetamidophenol
DChloropromazine hydrochloride
Question 109Single Answer
For a f – orbital the values of m1 are
A– 1, 0 + 1
B0, +1, + 2, + 3
C– 2, - 1, 0, + 1, + 2
D– 3, - 2, - 1, 0, + 1, + 2, + 3
Question 110Single Answer
Chloride ion and potassium ion are isoelectronic. Then
APotassium ion is relatively bigger
BDepends on the other cation and anion
CTheir size are same
DChloride ion is bigger than potassium ion
Question 111Single Answer
In a reversible reaction a catalyst will affect
AThe rate of forward reaction and reverse reaction
BNeither the forward reaction nor the rate of reverse reaction
CThe rate of forward reaction
DThe rate of reverse reaction
Question 112Single Answer
Pentavalence in phosphorous is more stable when compared to that of nitrogen even through they belong to same group is due to
AReactivity of phosphorous
BInert nature of nitrogen
CDissimilar electronic configuration
DLarger size of phosphorous atom
Question 113Single Answer
Aqueous solutions of hydrogen sulphide and sulphurdioxide when mixed together, yield
ASulphur trioxide and water
BHydrogen and sulphurous acid
CSulphur and water
DHydrogen peroxide and sulphur
Question 114Single Answer
A salt producing hydrocarbon among these compounds is
AEthane
BMethane
CEthene
DEthyne
Question 115Single Answer
Octane number is zero for
AN – octane
BIso – octane
CN – heptane
DIso – heptane
Question 116Single Answer
The intensive property among these quantities is
AEnthalpy
BMass/volume
CMass
DVolume
Question 117Single Answer
30g of Mg and 30g of oxygen are reacted and the residual mixture contains
A45g of MgO and 15 g of O2
B50g of MgO and 10 g of O2
C60g of MgO only
D40g of MgO and 20 g of O2
Question 118Single Answer
3 g of oxide of a metal is converted to chloride completely and it yielded 5 g of chloride. The equivalent weight of metal is
A12
B20
C33.25
D2.325
Question 119Single Answer
20 ml of 0.25 N strong acid and 30 ml 0.2 N of strong base are mixed; the resulting solution is
A0.02 N acidic
B0.025 N basic
C0.02 N basic
D0.025 N acidic
Question 120Single Answer
The rate of forward reaction is two times that of reverse reaction at a given temperature and identical concentration. Kequilibrium is
A2.5
B2.0
C0.5
D1.5
Question 121Single Answer
Ammonium ion is
ANeither an acid nor base
BBoth an acid and a base
CA conjugate acid
DΓ’β¬βΉA conjugate base
Question 122Single Answer
Water is a
AAmphoteric acid
BAprotic solvent
CProtophobic solvent
DProtophilic solvent
Question 123Single Answer
A chemical reaction was carried out at 300 K and 280 K. the rate constants were found to be K1 and K2 respectively, then:
AK2 = 0.25 K1
BK2 = 0.5 K1
CK2 = 4 K1
DK2 = 2K1
Question 124Single Answer
A smuggler could not carry gold by depositing iron and gold surface since:
AGold has higher standard reduction potential than iron
BGold has lower standard reduction potential than iron
CGold is denser
DIron rusts
Question 125Single Answer
A is an aqueous acid; B is an aqueous base. They are diluted separately, then:
ApH of A decreases and pH of B increases
BpH of A increases and pH of B decreases till pH in each case is 7
CpH of A and B increase
DpH of B and A decreases
Question 126Single Answer
kinetic theory of gases presumes that collision between the molecules to be perfectly elastic because:
Acollisions will not split the molecules
Bthe molecules are tiny
Cthe molecules are rigid
Dthe temperature remains constant irrespective collisions
Question 127Single Answer
zXM + 2He4 → 15P30 + 0n1. Then:
AZ = 12, M = 27
BZ = 13, M = 27
CZ = 12, M = 17
DΓ’β¬βΉZ = 13, M = 28
Question 128Single Answer
Bio- gas production is more useful when compared to the direct use of dung because
ABoth fuel value and fertilizer value are effectively utilized
BProduction of bio-gas involves less labour
CFuel is quickly produced
DThe fertilizer produced is a fluid
Question 129Single Answer
Compounds with high heat of formation are less stable because
AHigh temperature is required to synthesis them
BMolecules of such compounds are distorted
CIt is difficult to synthesis them
DEnergy rich state leads to instability
Question 130Single Answer
The volume of water to be added to 100 cm3 of 0.5 N H2SO4 to get decinormal concentration is: Γ’β¬βΉ
A400 cm3
B500 cm3
C450 cm3
D100 cm3
Question 131Single Answer
Heat of neutralization of weak acid and strong base is less than the heat of neutralization of strong acid an strong base due to
AEnergy has to be spent for the total dissociation of weak acid
BSalt of weak acid and strong base is not stable
CIncomplete dissociation of weak acid
DIncomplete neutralization of weak acid
Question 132Single Answer
A radio isotope will not emit
AGamma and alpha rays simultaneously
BGamma rays only
CAlpha and beta rays simultaneously
DBeta and gamma rays simultaneously
Question 133Single Answer
Heat treatment alters the properties of steel due to:
AChemical reaction on heating
BPartial rusting
CChange in the residual energy
DChange in the lattice structure due to differential rate of cooling
Question 134Single Answer
Chemical bond implies
AAttraction and impulses
BAttraction and repulsion balanced at a particular distance
CAttraction
DRepulsion
Question 135Single Answer
Grignard reagent is not prepared in aqueous medium but prepared in either medium. Because
AThe reagent reacts with water
BThe reagent becomes inactive in water
CIt is insoluble in water
DThe reagent is highly reactive in water
Question 136Single Answer
A lone pair of electrons in an atom implies:
AA pair of valence electrons not involved in bonding
BA pair of electrons involved in bonding
CA pair of electrons
DA pair of valence electrons
Question 137Single Answer
In the electrolytic refining of zinc
Agraphite is at the anode
Bthe impure metal is at the cathode
Cthe metal ion get reduced at the anode
Dacidified zinc sulphate is the electrolyte
Question 138Single Answer
In which of the following equilibrium systems is the rate of the backward reaction favoured by increase of pressure?Γ’β¬βΉ
A
PCl5 PCl3 +Cl2
B
2SO2 + O2 2SO3
CN2 + 3H2 2NH3
DN2 + O2 2NO
Question 139Single Answer
Halo alkane in the presence of alcoholic KOH undergoes:
AElimination
BPolymerisation
CDimerization
DΓ’β¬βΉSubstitution
Question 140Single Answer
Enthalpy of vaporization of benzene is +35.3kJ mol-1 at its boiling point, 80oC. The entropy change in the transition of the vapour to liquid at its boiling point in[JK-1mol-1] is
A-441
B-100
C+441
D+100
Question 141Single Answer
Reaction of aniline with benzaldehyde is:
APolymerisation
BCondensation
CAddition
DSubstitution
Question 142Single Answer
In chromite ore, the oxidation number of iron, and chromium are respectively
A+3,+2
B+3,+6
C+2,+6
D+2,+3
Question 143Single Answer
In order to decompose 9g water 142.5 kJ heat is required. Hence the enthalpy of formation of water is:Γ’β¬βΉ
A– 142.5 Kj
B+ 142.5 kJ
C– 285 Kj
D+ 285 kJ
Question 144Single Answer
The amount of heat evolved when 500 cm3 of 0.1 M HCl is mixed with 200 with 200 cm3 of 0.2 M NaOH is
A2.292 kJ
B1.292 kJ
C0.292 kJ
D3.392 kJ
Question 145Single Answer
A quantity of PCl5 was heated in a 10 dm3 vessel at 250 C PCl5 (g) PCl3 (g) + Cl2 (g) At equilibrium the vessel contains 0.1 mole of PCl5 and 0.2 mole of Cl2. The equilibrium constant of the reaction is:
A0.05
B0.02
C0.025
D0.04
Question 146Single Answer
An ester used as medicine is:
AEthyl benzoate
BMethyl salicylate
C
Methyl acetate
DEthyl acetate
Question 147Single Answer
Peroxide ion…………
(i) has five completely filled antibonding molecular orbitals
(ii) is diamagnetic
(iii) has bond order one
(iv) is isoelectronic with neon
Which one of these is correct?
A(ii) and (iii)
B(i), (ii) and (iv)
C(i), (ii) and (iii)
D(i) and (iv)
Question 148Single Answer
Which one of these is not true for benzene?
AIt forms only one type of monosubstituted product
BThere are three carbon-carbon single bonds and three carbon-carbon double bonds
CThe heat of hydrogenation of benzene is less than the theoretical value
DThe bond angle between the carbon-carbon bonds is 120o
Question 149Single Answer
A mixture of CaCl2 and NaCl weighing 4.44 g is treated with sodium carbonate solution to precipitate all the Ca2+ ions as calcium carbonate. The calcium carbonate so obtained is heated strongly to get 0.56 g of CaO. The percentage of NaCl in the mixture (atomic mass of Ca=40)is
A75
B30.6
C25
D69.4
Question 150Single Answer
Which one of the following non metals is not a poor conductor of electricity